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  "citation": "Krol, D., Harty, M.A., Rahman, N. (2025)  Differing 
n
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  "citation": "Krol, D. (2025). Differing effects of fertiliser use on 
            
8
effects of fertiliser use on nitrous oxide emissions from grassland 
8
nitrous oxide emissions from grassland sites in Ireland [Dataset]. 
            
9
sites in Ireland: Dataset. Teagasc Open Data Platform. ",
9
Teagasc - The Irish Agriculture and Food Development Authority. 
            
10
https://doi.org/10.82253/WNVY-5565",
            
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  "contact_email": "dominika.krol@teagasc.ie",
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  "contact_email": "dominika.krol@teagasc.ie",
            
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  "contact_name": "Dr Dominika Krol",
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  "contact_name": "Dr Dominika Krol",
            
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  "creator_user_id": "68d970d0-ff26-4dfe-ab51-46dde87e3f23",
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  "creator_user_id": "68d970d0-ff26-4dfe-ab51-46dde87e3f23",
            
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  "data_creator": [
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  "data_creator": [
            
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    "M.A. Harty (Teagasc)",
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    "M.A. Harty (Teagasc)",
            
17
    "N. Rahman (Teagasc)"
18
    "N. Rahman (Teagasc)"
            
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  ],
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  ],
            
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  "description_english": "Field experiments at six Irish grassland 
20
  "description_english": "Field experiments at six Irish grassland 
            
20
sites (2013\u20132014) examined the influence of nitrogen (N) 
21
sites (2013\u20132014) examined the influence of nitrogen (N) 
            
21
fertiliser type and application rate on nitrous oxide (N\u2082O) 
22
fertiliser type and application rate on nitrous oxide (N\u2082O) 
            
22
emissions. Calcium ammonium nitrate (CAN) replaced with urea-based 
23
emissions. Calcium ammonium nitrate (CAN) replaced with urea-based 
            
23
fertilisers, particularly when stabilised with inhibitors such as NBPT 
24
fertilisers, particularly when stabilised with inhibitors such as NBPT 
            
24
or DCD, reduced direct N\u2082O emissions by up to 80% while lowering 
25
or DCD, reduced direct N\u2082O emissions by up to 80% while lowering 
            
25
costs. Emission factors (EFs) were strongly influenced by fertiliser 
26
costs. Emission factors (EFs) were strongly influenced by fertiliser 
            
26
formulation and rate, with CAN consistently producing higher and more 
27
formulation and rate, with CAN consistently producing higher and more 
            
27
variable emissions than urea. Stabilised urea (urea + NBPT) was least 
28
variable emissions than urea. Stabilised urea (urea + NBPT) was least 
            
28
sensitive to increasing rates. Collectively, these studies highlight 
29
sensitive to increasing rates. Collectively, these studies highlight 
            
29
that fertiliser choice and rate are key management levers for 
30
that fertiliser choice and rate are key management levers for 
            
30
mitigating agricultural greenhouse gases and underscore the need for 
31
mitigating agricultural greenhouse gases and underscore the need for 
            
31
country-specific emission factors to improve national greenhouse gas 
32
country-specific emission factors to improve national greenhouse gas 
            
32
inventories.",
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inventories.",
            
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  "description_translated": "",
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  "description_translated": "",
            
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  "doi": "",
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  "doi": "doi.org/10.82253/WNVY-5565",
            
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  "equipment_used": "Closed static chambers\r\nGas Chromatography (GC) 
36
  "equipment_used": "Closed static chambers\r\nGas Chromatography (GC) 
            
36
with electron capture detectors (ECD)\r\nAquakem 600 discrete analyser 
37
with electron capture detectors (ECD)\r\nAquakem 600 discrete analyser 
            
37
(JC and MP)\r\nSkalar San++ continuous flow analyser (HB)\r\nSoil 
38
(JC and MP)\r\nSkalar San++ continuous flow analyser (HB)\r\nSoil 
            
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moisture measured using ML2x Theta Probe (Delta-T Devices) and logged 
39
moisture measured using ML2x Theta Probe (Delta-T Devices) and logged 
            
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with Campbell CR10X data loggers\r\n",
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with Campbell CR10X data loggers\r\n",
            
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  "funding_acknowledgment": "",
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  "funding_acknowledgment": "",
            
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  "geographic_coverage": "Johnstown Castle and Moorepark (Ireland), 
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  "geographic_coverage": "Johnstown Castle and Moorepark (Ireland), 
            
42
Hillsborough (Northern Ireland), with site-year replication (six 
43
Hillsborough (Northern Ireland), with site-year replication (six 
            
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site-years).",
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site-years).",
            
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liser-use-on-nitrous-oxide-emissions-from-grassland-sites-in-ireland",
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liser-use-on-nitrous-oxide-emissions-from-grassland-sites-in-ireland",
            
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    "name": "soil-environment-and-land-use-research",
            
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    "state": "active",
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    "state": "active",
            
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    "title": "Soil, Environment and Land-Use Research",
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    "title": "Soil, Environment and Land-Use Research",
            
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    "type": "organization"
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    "type": "organization"
            
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  "provenance": "Both studies used field experiments at six temperate 
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  "provenance": "Both studies used field experiments at six temperate 
            
79
grassland sites in Ireland (Johnstown Castle, Moorepark, and 
80
grassland sites in Ireland (Johnstown Castle, Moorepark, and 
            
80
Hillsborough) during 2013\u20132014, applying fertilisers in 
81
Hillsborough) during 2013\u20132014, applying fertilisers in 
            
81
replicated plots. Nitrous oxide (N\u2082O) fluxes were measured using 
82
replicated plots. Nitrous oxide (N\u2082O) fluxes were measured using 
            
82
the closed static chamber technique, with gas samples collected after 
83
the closed static chamber technique, with gas samples collected after 
            
83
chamber closure and analysed by gas chromatography with electron 
84
chamber closure and analysed by gas chromatography with electron 
            
84
capture detectors. Soil samples were taken regularly to assess mineral 
85
capture detectors. Soil samples were taken regularly to assess mineral 
            
85
nitrogen (NH\u2084\u207a and NO\u2083\u207b), while soil moisture, 
86
nitrogen (NH\u2084\u207a and NO\u2083\u207b), while soil moisture, 
            
86
temperature, and weather data were recorded using probes and nearby 
87
temperature, and weather data were recorded using probes and nearby 
            
87
meteorological stations. Fertiliser treatments included calcium 
88
meteorological stations. Fertiliser treatments included calcium 
            
88
ammonium nitrate (CAN), urea, and urea amended with stabilisers (e.g. 
89
ammonium nitrate (CAN), urea, and urea amended with stabilisers (e.g. 
            
89
NBPT, DCD), applied either at a single rate (Harty et al. 2016) or 
90
NBPT, DCD), applied either at a single rate (Harty et al. 2016) or 
            
90
across a range of rates (Rahman et al. 2021). Statistical analyses 
91
across a range of rates (Rahman et al. 2021). Statistical analyses 
            
91
(ANOVA, regression) were used to compare cumulative N\u2082O emissions 
92
(ANOVA, regression) were used to compare cumulative N\u2082O emissions 
            
92
and calculate emission factors.",
93
and calculate emission factors.",
            
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  "publish_to_public": "true",
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  "publish_to_public": "true",
            
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  "related_resource": [
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  "related_resource": [
            
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    "Harty, M.A., Forrestal, P.J., Watson, C.J., McGeough, K.L., 
96
    "Harty, M.A., Forrestal, P.J., Watson, C.J., McGeough, K.L., 
            
96
Carolan, R., Elliot, C., Krol, D., Laughlin, R.J., Richards, K.G. & 
97
Carolan, R., Elliot, C., Krol, D., Laughlin, R.J., Richards, K.G. & 
            
97
Lanigan, G.J., 2016. Reducing nitrous oxide emissions by changing N 
98
Lanigan, G.J., 2016. Reducing nitrous oxide emissions by changing N 
            
98
fertiliser use from calcium ammonium nitrate (CAN) to urea based 
99
fertiliser use from calcium ammonium nitrate (CAN) to urea based 
            
99
formulations. Science of the Total Environment, 563\u2013564, 
100
formulations. Science of the Total Environment, 563\u2013564, 
            
100
pp.576\u2013586. https://doi.org/10.1016/j.scitotenv.2016.04.120",
101
pp.576\u2013586. https://doi.org/10.1016/j.scitotenv.2016.04.120",
            
101
    "Rahman, N., Richards, K.G., Harty, M.A., Watson, C.J., Carolan, 
102
    "Rahman, N., Richards, K.G., Harty, M.A., Watson, C.J., Carolan, 
            
102
R., Krol, D., Lanigan, G.J. & Forrestal, P.J., 2021. Differing effects 
103
R., Krol, D., Lanigan, G.J. & Forrestal, P.J., 2021. Differing effects 
            
103
of increasing calcium ammonium nitrate, urea and urea + NBPT 
104
of increasing calcium ammonium nitrate, urea and urea + NBPT 
            
104
fertiliser rates on nitrous oxide emission factors at six temperate 
105
fertiliser rates on nitrous oxide emission factors at six temperate 
            
105
grassland sites in Ireland. Agriculture, Ecosystems & Environment, 
106
grassland sites in Ireland. Agriculture, Ecosystems & Environment, 
            
106
313, 107382. https://doi.org/10.1016/j.agee.2021.107382"
107
313, 107382. https://doi.org/10.1016/j.agee.2021.107382"
            
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      "id": "94d82976-af16-4e31-bae6-bd64e1592c03",
            
371
      "name": "Nitrogen fertiliser",
372
      "name": "Nitrogen fertiliser",
            
372
      "state": "active",
373
      "state": "active",
            
373
      "vocabulary_id": null
374
      "vocabulary_id": null
            
374
    },
375
    },
            
375
    {
376
    {
            
376
      "display_name": "Nitrous oxide emissions",
377
      "display_name": "Nitrous oxide emissions",
            
377
      "id": "50833976-9648-4da9-b17f-c62d5c2b2fc9",
378
      "id": "50833976-9648-4da9-b17f-c62d5c2b2fc9",
            
378
      "name": "Nitrous oxide emissions",
379
      "name": "Nitrous oxide emissions",
            
379
      "state": "active",
380
      "state": "active",
            
380
      "vocabulary_id": null
381
      "vocabulary_id": null
            
381
    },
382
    },
            
382
    {
383
    {
            
383
      "display_name": "Urea",
384
      "display_name": "Urea",
            
384
      "id": "79c9cb44-1505-4d8d-9007-773466980bf5",
385
      "id": "79c9cb44-1505-4d8d-9007-773466980bf5",
            
385
      "name": "Urea",
386
      "name": "Urea",
            
386
      "state": "active",
387
      "state": "active",
            
387
      "vocabulary_id": null
388
      "vocabulary_id": null
            
388
    }
389
    }
            
389
  ],
390
  ],
            
390
  "temporal": "2013-2014",
391
  "temporal": "2013-2014",
            
391
  "theme": "crops_environment_and_land_use",
392
  "theme": "crops_environment_and_land_use",
            
392
  "title": "Differing effects of fertiliser use on nitrous oxide 
393
  "title": "Differing effects of fertiliser use on nitrous oxide 
            
393
emissions from grassland sites in Ireland",
394
emissions from grassland sites in Ireland",
            
394
  "title_translated": {
395
  "title_translated": {
            
395
    "en": "Differing effects of fertiliser use on nitrous oxide 
396
    "en": "Differing effects of fertiliser use on nitrous oxide 
            
396
emissions from grassland sites in Ireland",
397
emissions from grassland sites in Ireland",
            
397
    "ga": ""
398
    "ga": ""
            
398
  },
399
  },
            
399
  "type": "dataset",
400
  "type": "dataset",
            
400
  "update_frequency": "",
401
  "update_frequency": "",
            
401
  "url": "",
402
  "url": "",
            
402
  "version": "",
403
  "version": "",
            
403
  "vertical_extent": ""
404
  "vertical_extent": ""
            
404
}
405
}