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| 7 | "citation": "Krol, D. (2025). Differing effects of fertiliser use on | 7 | "citation": "Krol, D. (2025). Differing effects of fertiliser use on | ||
| 8 | nitrous oxide emissions from grassland sites in Ireland [Dataset]. | 8 | nitrous oxide emissions from grassland sites in Ireland [Dataset]. | ||
| 9 | Teagasc - The Irish Agriculture and Food Development Authority. | 9 | Teagasc - The Irish Agriculture and Food Development Authority. | ||
| 10 | https://doi.org/10.82253/WNVY-5565", | 10 | https://doi.org/10.82253/WNVY-5565", | ||
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| 13 | "contact_email": "dominika.krol@teagasc.ie", | 13 | "contact_email": "dominika.krol@teagasc.ie", | ||
| 14 | "contact_name": "Dr Dominika Krol", | 14 | "contact_name": "Dr Dominika Krol", | ||
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| 16 | "data_creator": [ | 16 | "data_creator": [ | ||
| 17 | "M.A. Harty (Teagasc)", | 17 | "M.A. Harty (Teagasc)", | ||
| 18 | "N. Rahman (Teagasc)" | 18 | "N. Rahman (Teagasc)" | ||
| 19 | ], | 19 | ], | ||
| 20 | "doi": "doi.org/10.82253/WNVY-5565", | 20 | "doi": "doi.org/10.82253/WNVY-5565", | ||
| 21 | "equipment_used": "Closed static chambers\r\nGas Chromatography (GC) | 21 | "equipment_used": "Closed static chambers\r\nGas Chromatography (GC) | ||
| 22 | with electron capture detectors (ECD)\r\nAquakem 600 discrete analyser | 22 | with electron capture detectors (ECD)\r\nAquakem 600 discrete analyser | ||
| 23 | (JC and MP)\r\nSkalar San++ continuous flow analyser (HB)\r\nSoil | 23 | (JC and MP)\r\nSkalar San++ continuous flow analyser (HB)\r\nSoil | ||
| 24 | moisture measured using ML2x Theta Probe (Delta-T Devices) and logged | 24 | moisture measured using ML2x Theta Probe (Delta-T Devices) and logged | ||
| 25 | with Campbell CR10X data loggers\r\n", | 25 | with Campbell CR10X data loggers\r\n", | ||
| 26 | "funding_acknowledgment": "", | 26 | "funding_acknowledgment": "", | ||
| 27 | "geographic_coverage": "Johnstown Castle and Moorepark (Ireland), | 27 | "geographic_coverage": "Johnstown Castle and Moorepark (Ireland), | ||
| 28 | Hillsborough (Northern Ireland), with site-year replication (six | 28 | Hillsborough (Northern Ireland), with site-year replication (six | ||
| 29 | site-years).", | 29 | site-years).", | ||
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| 42 | "name": | 42 | "name": | ||
| 43 | liser-use-on-nitrous-oxide-emissions-from-grassland-sites-in-ireland", | 43 | liser-use-on-nitrous-oxide-emissions-from-grassland-sites-in-ireland", | ||
| 44 | "notes_translated": { | 44 | "notes_translated": { | ||
| 45 | "en": "Field experiments at six Irish grassland sites | 45 | "en": "Field experiments at six Irish grassland sites | ||
| 46 | (2013\u20132014) examined the influence of nitrogen (N) fertiliser | 46 | (2013\u20132014) examined the influence of nitrogen (N) fertiliser | ||
| 47 | type and application rate on nitrous oxide (N\u2082O) emissions. | 47 | type and application rate on nitrous oxide (N\u2082O) emissions. | ||
| 48 | Calcium ammonium nitrate (CAN) replaced with urea-based fertilisers, | 48 | Calcium ammonium nitrate (CAN) replaced with urea-based fertilisers, | ||
| 49 | particularly when stabilised with inhibitors such as NBPT or DCD, | 49 | particularly when stabilised with inhibitors such as NBPT or DCD, | ||
| 50 | reduced direct N\u2082O emissions by up to 80% while lowering costs. | 50 | reduced direct N\u2082O emissions by up to 80% while lowering costs. | ||
| 51 | Emission factors (EFs) were strongly influenced by fertiliser | 51 | Emission factors (EFs) were strongly influenced by fertiliser | ||
| 52 | formulation and rate, with CAN consistently producing higher and more | 52 | formulation and rate, with CAN consistently producing higher and more | ||
| 53 | variable emissions than urea. Stabilised urea (urea + NBPT) was least | 53 | variable emissions than urea. Stabilised urea (urea + NBPT) was least | ||
| 54 | sensitive to increasing rates. Collectively, these studies highlight | 54 | sensitive to increasing rates. Collectively, these studies highlight | ||
| 55 | that fertiliser choice and rate are key management levers for | 55 | that fertiliser choice and rate are key management levers for | ||
| 56 | mitigating agricultural greenhouse gases and underscore the need for | 56 | mitigating agricultural greenhouse gases and underscore the need for | ||
| 57 | country-specific emission factors to improve national greenhouse gas | 57 | country-specific emission factors to improve national greenhouse gas | ||
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| 81 | "provenance": "Both studies used field experiments at six temperate | 81 | "provenance": "Both studies used field experiments at six temperate | ||
| 82 | grassland sites in Ireland (Johnstown Castle, Moorepark, and | 82 | grassland sites in Ireland (Johnstown Castle, Moorepark, and | ||
| 83 | Hillsborough) during 2013\u20132014, applying fertilisers in | 83 | Hillsborough) during 2013\u20132014, applying fertilisers in | ||
| 84 | replicated plots. Nitrous oxide (N\u2082O) fluxes were measured using | 84 | replicated plots. Nitrous oxide (N\u2082O) fluxes were measured using | ||
| 85 | the closed static chamber technique, with gas samples collected after | 85 | the closed static chamber technique, with gas samples collected after | ||
| 86 | chamber closure and analysed by gas chromatography with electron | 86 | chamber closure and analysed by gas chromatography with electron | ||
| 87 | capture detectors. Soil samples were taken regularly to assess mineral | 87 | capture detectors. Soil samples were taken regularly to assess mineral | ||
| 88 | nitrogen (NH\u2084\u207a and NO\u2083\u207b), while soil moisture, | 88 | nitrogen (NH\u2084\u207a and NO\u2083\u207b), while soil moisture, | ||
| 89 | temperature, and weather data were recorded using probes and nearby | 89 | temperature, and weather data were recorded using probes and nearby | ||
| 90 | meteorological stations. Fertiliser treatments included calcium | 90 | meteorological stations. Fertiliser treatments included calcium | ||
| 91 | ammonium nitrate (CAN), urea, and urea amended with stabilisers (e.g. | 91 | ammonium nitrate (CAN), urea, and urea amended with stabilisers (e.g. | ||
| 92 | NBPT, DCD), applied either at a single rate (Harty et al. 2016) or | 92 | NBPT, DCD), applied either at a single rate (Harty et al. 2016) or | ||
| 93 | across a range of rates (Rahman et al. 2021). Statistical analyses | 93 | across a range of rates (Rahman et al. 2021). Statistical analyses | ||
| 94 | (ANOVA, regression) were used to compare cumulative N\u2082O emissions | 94 | (ANOVA, regression) were used to compare cumulative N\u2082O emissions | ||
| 95 | and calculate emission factors.", | 95 | and calculate emission factors.", | ||
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| 97 | "related_resource": [ | 97 | "related_resource": [ | ||
| 98 | "Harty, M.A., Forrestal, P.J., Watson, C.J., McGeough, K.L., | 98 | "Harty, M.A., Forrestal, P.J., Watson, C.J., McGeough, K.L., | ||
| 99 | Carolan, R., Elliot, C., Krol, D., Laughlin, R.J., Richards, K.G. & | 99 | Carolan, R., Elliot, C., Krol, D., Laughlin, R.J., Richards, K.G. & | ||
| 100 | Lanigan, G.J., 2016. Reducing nitrous oxide emissions by changing N | 100 | Lanigan, G.J., 2016. Reducing nitrous oxide emissions by changing N | ||
| 101 | fertiliser use from calcium ammonium nitrate (CAN) to urea based | 101 | fertiliser use from calcium ammonium nitrate (CAN) to urea based | ||
| 102 | formulations. Science of the Total Environment, 563\u2013564, | 102 | formulations. Science of the Total Environment, 563\u2013564, | ||
| 103 | pp.576\u2013586. https://doi.org/10.1016/j.scitotenv.2016.04.120", | 103 | pp.576\u2013586. https://doi.org/10.1016/j.scitotenv.2016.04.120", | ||
| 104 | "Rahman, N., Richards, K.G., Harty, M.A., Watson, C.J., Carolan, | 104 | "Rahman, N., Richards, K.G., Harty, M.A., Watson, C.J., Carolan, | ||
| 105 | R., Krol, D., Lanigan, G.J. & Forrestal, P.J., 2021. Differing effects | 105 | R., Krol, D., Lanigan, G.J. & Forrestal, P.J., 2021. Differing effects | ||
| 106 | of increasing calcium ammonium nitrate, urea and urea + NBPT | 106 | of increasing calcium ammonium nitrate, urea and urea + NBPT | ||
| 107 | fertiliser rates on nitrous oxide emission factors at six temperate | 107 | fertiliser rates on nitrous oxide emission factors at six temperate | ||
| 108 | grassland sites in Ireland. Agriculture, Ecosystems & Environment, | 108 | grassland sites in Ireland. Agriculture, Ecosystems & Environment, | ||
| 109 | 313, 107382. https://doi.org/10.1016/j.agee.2021.107382" | 109 | 313, 107382. https://doi.org/10.1016/j.agee.2021.107382" | ||
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