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  "citation": "Krol, D. (2025). Differing effects of fertiliser use on 
7
  "citation": "Krol, D. (2025). Differing effects of fertiliser use on 
            
8
nitrous oxide emissions from grassland sites in Ireland [Dataset]. 
8
nitrous oxide emissions from grassland sites in Ireland [Dataset]. 
            
9
Teagasc - The Irish Agriculture and Food Development Authority. 
9
Teagasc - The Irish Agriculture and Food Development Authority. 
            
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https://doi.org/10.82253/WNVY-5565",
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https://doi.org/10.82253/WNVY-5565",
            
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  "contact_email": "dominika.krol@teagasc.ie",
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  "contact_email": "dominika.krol@teagasc.ie",
            
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  "contact_name": "Dr Dominika Krol",
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  "contact_name": "Dr Dominika Krol",
            
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  "data_creator": [
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  "data_creator": [
            
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    "M.A. Harty (Teagasc)",
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    "M.A. Harty (Teagasc)",
            
18
    "N. Rahman (Teagasc)"
18
    "N. Rahman (Teagasc)"
            
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  ],
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  ],
            
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  "description_english": "Field experiments at six Irish grassland 
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  "description_english": "Field experiments at six Irish grassland 
            
21
sites (2013\u20132014) examined the influence of nitrogen (N) 
21
sites (2013\u20132014) examined the influence of nitrogen (N) 
            
22
fertiliser type and application rate on nitrous oxide (N\u2082O) 
22
fertiliser type and application rate on nitrous oxide (N\u2082O) 
            
23
emissions. Calcium ammonium nitrate (CAN) replaced with urea-based 
23
emissions. Calcium ammonium nitrate (CAN) replaced with urea-based 
            
24
fertilisers, particularly when stabilised with inhibitors such as NBPT 
24
fertilisers, particularly when stabilised with inhibitors such as NBPT 
            
25
or DCD, reduced direct N\u2082O emissions by up to 80% while lowering 
25
or DCD, reduced direct N\u2082O emissions by up to 80% while lowering 
            
26
costs. Emission factors (EFs) were strongly influenced by fertiliser 
26
costs. Emission factors (EFs) were strongly influenced by fertiliser 
            
27
formulation and rate, with CAN consistently producing higher and more 
27
formulation and rate, with CAN consistently producing higher and more 
            
28
variable emissions than urea. Stabilised urea (urea + NBPT) was least 
28
variable emissions than urea. Stabilised urea (urea + NBPT) was least 
            
29
sensitive to increasing rates. Collectively, these studies highlight 
29
sensitive to increasing rates. Collectively, these studies highlight 
            
30
that fertiliser choice and rate are key management levers for 
30
that fertiliser choice and rate are key management levers for 
            
31
mitigating agricultural greenhouse gases and underscore the need for 
31
mitigating agricultural greenhouse gases and underscore the need for 
            
32
country-specific emission factors to improve national greenhouse gas 
32
country-specific emission factors to improve national greenhouse gas 
            
33
inventories.",
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inventories.",
            
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  "description_translated": "",
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  "description_translated": "",
            
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  "doi": "doi.org/10.82253/WNVY-5565",
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  "doi": "doi.org/10.82253/WNVY-5565",
            
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  "equipment_used": "Closed static chambers\r\nGas Chromatography (GC) 
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  "equipment_used": "Closed static chambers\r\nGas Chromatography (GC) 
            
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with electron capture detectors (ECD)\r\nAquakem 600 discrete analyser 
37
with electron capture detectors (ECD)\r\nAquakem 600 discrete analyser 
            
38
(JC and MP)\r\nSkalar San++ continuous flow analyser (HB)\r\nSoil 
38
(JC and MP)\r\nSkalar San++ continuous flow analyser (HB)\r\nSoil 
            
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moisture measured using ML2x Theta Probe (Delta-T Devices) and logged 
39
moisture measured using ML2x Theta Probe (Delta-T Devices) and logged 
            
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with Campbell CR10X data loggers\r\n",
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with Campbell CR10X data loggers\r\n",
            
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  "funding_acknowledgment": "",
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  "funding_acknowledgment": "",
            
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  "geographic_coverage": "Johnstown Castle and Moorepark (Ireland), 
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  "geographic_coverage": "Johnstown Castle and Moorepark (Ireland), 
            
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Hillsborough (Northern Ireland), with site-year replication (six 
43
Hillsborough (Northern Ireland), with site-year replication (six 
            
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site-years).",
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site-years).",
            
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liser-use-on-nitrous-oxide-emissions-from-grassland-sites-in-ireland",
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liser-use-on-nitrous-oxide-emissions-from-grassland-sites-in-ireland",
            
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    "en": "Field experiments at six Irish grassland sites 
            
61
(2013\u20132014) examined the influence of nitrogen (N) fertiliser 
            
62
type and application rate on nitrous oxide (N\u2082O) emissions. 
            
63
Calcium ammonium nitrate (CAN) replaced with urea-based fertilisers, 
            
64
particularly when stabilised with inhibitors such as NBPT or DCD, 
            
65
reduced direct N\u2082O emissions by up to 80% while lowering costs. 
            
66
Emission factors (EFs) were strongly influenced by fertiliser 
            
67
formulation and rate, with CAN consistently producing higher and more 
            
68
variable emissions than urea. Stabilised urea (urea + NBPT) was least 
            
69
sensitive to increasing rates. Collectively, these studies highlight 
            
70
that fertiliser choice and rate are key management levers for 
            
71
mitigating agricultural greenhouse gases and underscore the need for 
            
72
country-specific emission factors to improve national greenhouse gas 
            
73
inventories.",
            
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    "ga": ""
            
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    "state": "active",
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    "state": "active",
            
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    "title": "Soil, Environment and Land-Use Research",
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    "title": "Soil, Environment and Land-Use Research",
            
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    "type": "organization"
            
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  "provenance": "Both studies used field experiments at six temperate 
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  "provenance": "Both studies used field experiments at six temperate 
            
80
grassland sites in Ireland (Johnstown Castle, Moorepark, and 
97
grassland sites in Ireland (Johnstown Castle, Moorepark, and 
            
81
Hillsborough) during 2013\u20132014, applying fertilisers in 
98
Hillsborough) during 2013\u20132014, applying fertilisers in 
            
82
replicated plots. Nitrous oxide (N\u2082O) fluxes were measured using 
99
replicated plots. Nitrous oxide (N\u2082O) fluxes were measured using 
            
83
the closed static chamber technique, with gas samples collected after 
100
the closed static chamber technique, with gas samples collected after 
            
84
chamber closure and analysed by gas chromatography with electron 
101
chamber closure and analysed by gas chromatography with electron 
            
85
capture detectors. Soil samples were taken regularly to assess mineral 
102
capture detectors. Soil samples were taken regularly to assess mineral 
            
86
nitrogen (NH\u2084\u207a and NO\u2083\u207b), while soil moisture, 
103
nitrogen (NH\u2084\u207a and NO\u2083\u207b), while soil moisture, 
            
87
temperature, and weather data were recorded using probes and nearby 
104
temperature, and weather data were recorded using probes and nearby 
            
88
meteorological stations. Fertiliser treatments included calcium 
105
meteorological stations. Fertiliser treatments included calcium 
            
89
ammonium nitrate (CAN), urea, and urea amended with stabilisers (e.g. 
106
ammonium nitrate (CAN), urea, and urea amended with stabilisers (e.g. 
            
90
NBPT, DCD), applied either at a single rate (Harty et al. 2016) or 
107
NBPT, DCD), applied either at a single rate (Harty et al. 2016) or 
            
91
across a range of rates (Rahman et al. 2021). Statistical analyses 
108
across a range of rates (Rahman et al. 2021). Statistical analyses 
            
92
(ANOVA, regression) were used to compare cumulative N\u2082O emissions 
109
(ANOVA, regression) were used to compare cumulative N\u2082O emissions 
            
93
and calculate emission factors.",
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and calculate emission factors.",
            
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  "related_resource": [
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  "related_resource": [
            
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    "Harty, M.A., Forrestal, P.J., Watson, C.J., McGeough, K.L., 
113
    "Harty, M.A., Forrestal, P.J., Watson, C.J., McGeough, K.L., 
            
97
Carolan, R., Elliot, C., Krol, D., Laughlin, R.J., Richards, K.G. & 
114
Carolan, R., Elliot, C., Krol, D., Laughlin, R.J., Richards, K.G. & 
            
98
Lanigan, G.J., 2016. Reducing nitrous oxide emissions by changing N 
115
Lanigan, G.J., 2016. Reducing nitrous oxide emissions by changing N 
            
99
fertiliser use from calcium ammonium nitrate (CAN) to urea based 
116
fertiliser use from calcium ammonium nitrate (CAN) to urea based 
            
100
formulations. Science of the Total Environment, 563\u2013564, 
117
formulations. Science of the Total Environment, 563\u2013564, 
            
101
pp.576\u2013586. https://doi.org/10.1016/j.scitotenv.2016.04.120",
118
pp.576\u2013586. https://doi.org/10.1016/j.scitotenv.2016.04.120",
            
102
    "Rahman, N., Richards, K.G., Harty, M.A., Watson, C.J., Carolan, 
119
    "Rahman, N., Richards, K.G., Harty, M.A., Watson, C.J., Carolan, 
            
103
R., Krol, D., Lanigan, G.J. & Forrestal, P.J., 2021. Differing effects 
120
R., Krol, D., Lanigan, G.J. & Forrestal, P.J., 2021. Differing effects 
            
104
of increasing calcium ammonium nitrate, urea and urea + NBPT 
121
of increasing calcium ammonium nitrate, urea and urea + NBPT 
            
105
fertiliser rates on nitrous oxide emission factors at six temperate 
122
fertiliser rates on nitrous oxide emission factors at six temperate 
            
106
grassland sites in Ireland. Agriculture, Ecosystems & Environment, 
123
grassland sites in Ireland. Agriculture, Ecosystems & Environment, 
            
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313, 107382. https://doi.org/10.1016/j.agee.2021.107382"
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313, 107382. https://doi.org/10.1016/j.agee.2021.107382"
            
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      "name": "Greenhouse gas emissions",
            
359
      "state": "active",
376
      "state": "active",
            
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      "vocabulary_id": null
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      "vocabulary_id": null
            
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    },
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    },
            
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    {
379
    {
            
363
      "display_name": "Nitrification inhibitor dicyandiamide",
380
      "display_name": "Nitrification inhibitor dicyandiamide",
            
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      "id": "e362b4c2-0265-4bb3-bfbd-cf82976639ca",
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      "id": "e362b4c2-0265-4bb3-bfbd-cf82976639ca",
            
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      "name": "Nitrification inhibitor dicyandiamide",
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      "name": "Nitrification inhibitor dicyandiamide",
            
366
      "state": "active",
383
      "state": "active",
            
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      "vocabulary_id": null
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      "vocabulary_id": null
            
368
    },
385
    },
            
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    {
386
    {
            
370
      "display_name": "Nitrogen fertiliser",
387
      "display_name": "Nitrogen fertiliser",
            
371
      "id": "94d82976-af16-4e31-bae6-bd64e1592c03",
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      "id": "94d82976-af16-4e31-bae6-bd64e1592c03",
            
372
      "name": "Nitrogen fertiliser",
389
      "name": "Nitrogen fertiliser",
            
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      "state": "active",
390
      "state": "active",
            
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      "vocabulary_id": null
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      "vocabulary_id": null
            
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    },
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    },
            
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    {
393
    {
            
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      "display_name": "Nitrous oxide emissions",
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      "display_name": "Nitrous oxide emissions",
            
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      "id": "50833976-9648-4da9-b17f-c62d5c2b2fc9",
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      "id": "50833976-9648-4da9-b17f-c62d5c2b2fc9",
            
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      "name": "Nitrous oxide emissions",
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      "name": "Nitrous oxide emissions",
            
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      "state": "active",
397
      "state": "active",
            
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      "vocabulary_id": null
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      "vocabulary_id": null
            
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    },
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    },
            
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    {
400
    {
            
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      "display_name": "Urea",
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      "display_name": "Urea",
            
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      "id": "79c9cb44-1505-4d8d-9007-773466980bf5",
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      "id": "79c9cb44-1505-4d8d-9007-773466980bf5",
            
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      "name": "Urea",
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      "name": "Urea",
            
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      "state": "active",
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      "state": "active",
            
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      "vocabulary_id": null
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      "vocabulary_id": null
            
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    }
406
    }
            
390
  ],
407
  ],
            
391
  "temporal": "2013-2014",
408
  "temporal": "2013-2014",
            
392
  "theme": "crops_environment_and_land_use",
409
  "theme": "crops_environment_and_land_use",
            
393
  "title": "Differing effects of fertiliser use on nitrous oxide 
410
  "title": "Differing effects of fertiliser use on nitrous oxide 
            
394
emissions from grassland sites in Ireland",
411
emissions from grassland sites in Ireland",
            
395
  "title_translated": {
412
  "title_translated": {
            
396
    "en": "Differing effects of fertiliser use on nitrous oxide 
413
    "en": "Differing effects of fertiliser use on nitrous oxide 
            
397
emissions from grassland sites in Ireland",
414
emissions from grassland sites in Ireland",
            
398
    "ga": ""
415
    "ga": ""
            
399
  },
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  },
            
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  "type": "dataset",
417
  "type": "dataset",
            
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  "update_frequency": "",
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  "update_frequency": "",
            
402
  "url": "",
419
  "url": "",
            
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  "version": "",
420
  "version": "",
            
404
  "vertical_extent": ""
421
  "vertical_extent": ""
            
405
}
422
}