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in Differing effects of fertiliser use on nitrous oxide emissions from grassland sites in Ireland
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7 | "citation": "Krol, D. (2025). Differing effects of fertiliser use on | 7 | "citation": "Krol, D. (2025). Differing effects of fertiliser use on | ||
8 | nitrous oxide emissions from grassland sites in Ireland [Dataset]. | 8 | nitrous oxide emissions from grassland sites in Ireland [Dataset]. | ||
9 | Teagasc - The Irish Agriculture and Food Development Authority. | 9 | Teagasc - The Irish Agriculture and Food Development Authority. | ||
10 | https://doi.org/10.82253/WNVY-5565", | 10 | https://doi.org/10.82253/WNVY-5565", | ||
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13 | "contact_email": "dominika.krol@teagasc.ie", | 13 | "contact_email": "dominika.krol@teagasc.ie", | ||
14 | "contact_name": "Dr Dominika Krol", | 14 | "contact_name": "Dr Dominika Krol", | ||
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16 | "data_creator": [ | 16 | "data_creator": [ | ||
17 | "M.A. Harty (Teagasc)", | 17 | "M.A. Harty (Teagasc)", | ||
18 | "N. Rahman (Teagasc)" | 18 | "N. Rahman (Teagasc)" | ||
19 | ], | 19 | ], | ||
20 | "description_english": "Field experiments at six Irish grassland | 20 | "description_english": "Field experiments at six Irish grassland | ||
21 | sites (2013\u20132014) examined the influence of nitrogen (N) | 21 | sites (2013\u20132014) examined the influence of nitrogen (N) | ||
22 | fertiliser type and application rate on nitrous oxide (N\u2082O) | 22 | fertiliser type and application rate on nitrous oxide (N\u2082O) | ||
23 | emissions. Calcium ammonium nitrate (CAN) replaced with urea-based | 23 | emissions. Calcium ammonium nitrate (CAN) replaced with urea-based | ||
24 | fertilisers, particularly when stabilised with inhibitors such as NBPT | 24 | fertilisers, particularly when stabilised with inhibitors such as NBPT | ||
25 | or DCD, reduced direct N\u2082O emissions by up to 80% while lowering | 25 | or DCD, reduced direct N\u2082O emissions by up to 80% while lowering | ||
26 | costs. Emission factors (EFs) were strongly influenced by fertiliser | 26 | costs. Emission factors (EFs) were strongly influenced by fertiliser | ||
27 | formulation and rate, with CAN consistently producing higher and more | 27 | formulation and rate, with CAN consistently producing higher and more | ||
28 | variable emissions than urea. Stabilised urea (urea + NBPT) was least | 28 | variable emissions than urea. Stabilised urea (urea + NBPT) was least | ||
29 | sensitive to increasing rates. Collectively, these studies highlight | 29 | sensitive to increasing rates. Collectively, these studies highlight | ||
30 | that fertiliser choice and rate are key management levers for | 30 | that fertiliser choice and rate are key management levers for | ||
31 | mitigating agricultural greenhouse gases and underscore the need for | 31 | mitigating agricultural greenhouse gases and underscore the need for | ||
32 | country-specific emission factors to improve national greenhouse gas | 32 | country-specific emission factors to improve national greenhouse gas | ||
33 | inventories.", | 33 | inventories.", | ||
34 | "description_translated": "", | 34 | "description_translated": "", | ||
35 | "doi": "doi.org/10.82253/WNVY-5565", | 35 | "doi": "doi.org/10.82253/WNVY-5565", | ||
36 | "equipment_used": "Closed static chambers\r\nGas Chromatography (GC) | 36 | "equipment_used": "Closed static chambers\r\nGas Chromatography (GC) | ||
37 | with electron capture detectors (ECD)\r\nAquakem 600 discrete analyser | 37 | with electron capture detectors (ECD)\r\nAquakem 600 discrete analyser | ||
38 | (JC and MP)\r\nSkalar San++ continuous flow analyser (HB)\r\nSoil | 38 | (JC and MP)\r\nSkalar San++ continuous flow analyser (HB)\r\nSoil | ||
39 | moisture measured using ML2x Theta Probe (Delta-T Devices) and logged | 39 | moisture measured using ML2x Theta Probe (Delta-T Devices) and logged | ||
40 | with Campbell CR10X data loggers\r\n", | 40 | with Campbell CR10X data loggers\r\n", | ||
41 | "funding_acknowledgment": "", | 41 | "funding_acknowledgment": "", | ||
42 | "geographic_coverage": "Johnstown Castle and Moorepark (Ireland), | 42 | "geographic_coverage": "Johnstown Castle and Moorepark (Ireland), | ||
43 | Hillsborough (Northern Ireland), with site-year replication (six | 43 | Hillsborough (Northern Ireland), with site-year replication (six | ||
44 | site-years).", | 44 | site-years).", | ||
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58 | liser-use-on-nitrous-oxide-emissions-from-grassland-sites-in-ireland", | 58 | liser-use-on-nitrous-oxide-emissions-from-grassland-sites-in-ireland", | ||
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60 | "en": "Field experiments at six Irish grassland sites | ||||
61 | (2013\u20132014) examined the influence of nitrogen (N) fertiliser | ||||
62 | type and application rate on nitrous oxide (N\u2082O) emissions. | ||||
63 | Calcium ammonium nitrate (CAN) replaced with urea-based fertilisers, | ||||
64 | particularly when stabilised with inhibitors such as NBPT or DCD, | ||||
65 | reduced direct N\u2082O emissions by up to 80% while lowering costs. | ||||
66 | Emission factors (EFs) were strongly influenced by fertiliser | ||||
67 | formulation and rate, with CAN consistently producing higher and more | ||||
68 | variable emissions than urea. Stabilised urea (urea + NBPT) was least | ||||
69 | sensitive to increasing rates. Collectively, these studies highlight | ||||
70 | that fertiliser choice and rate are key management levers for | ||||
71 | mitigating agricultural greenhouse gases and underscore the need for | ||||
72 | country-specific emission factors to improve national greenhouse gas | ||||
73 | inventories.", | ||||
74 | "ga": "" | ||||
75 | }, | ||||
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79 | "provenance": "Both studies used field experiments at six temperate | 96 | "provenance": "Both studies used field experiments at six temperate | ||
80 | grassland sites in Ireland (Johnstown Castle, Moorepark, and | 97 | grassland sites in Ireland (Johnstown Castle, Moorepark, and | ||
81 | Hillsborough) during 2013\u20132014, applying fertilisers in | 98 | Hillsborough) during 2013\u20132014, applying fertilisers in | ||
82 | replicated plots. Nitrous oxide (N\u2082O) fluxes were measured using | 99 | replicated plots. Nitrous oxide (N\u2082O) fluxes were measured using | ||
83 | the closed static chamber technique, with gas samples collected after | 100 | the closed static chamber technique, with gas samples collected after | ||
84 | chamber closure and analysed by gas chromatography with electron | 101 | chamber closure and analysed by gas chromatography with electron | ||
85 | capture detectors. Soil samples were taken regularly to assess mineral | 102 | capture detectors. Soil samples were taken regularly to assess mineral | ||
86 | nitrogen (NH\u2084\u207a and NO\u2083\u207b), while soil moisture, | 103 | nitrogen (NH\u2084\u207a and NO\u2083\u207b), while soil moisture, | ||
87 | temperature, and weather data were recorded using probes and nearby | 104 | temperature, and weather data were recorded using probes and nearby | ||
88 | meteorological stations. Fertiliser treatments included calcium | 105 | meteorological stations. Fertiliser treatments included calcium | ||
89 | ammonium nitrate (CAN), urea, and urea amended with stabilisers (e.g. | 106 | ammonium nitrate (CAN), urea, and urea amended with stabilisers (e.g. | ||
90 | NBPT, DCD), applied either at a single rate (Harty et al. 2016) or | 107 | NBPT, DCD), applied either at a single rate (Harty et al. 2016) or | ||
91 | across a range of rates (Rahman et al. 2021). Statistical analyses | 108 | across a range of rates (Rahman et al. 2021). Statistical analyses | ||
92 | (ANOVA, regression) were used to compare cumulative N\u2082O emissions | 109 | (ANOVA, regression) were used to compare cumulative N\u2082O emissions | ||
93 | and calculate emission factors.", | 110 | and calculate emission factors.", | ||
n | 94 | "publish_to_public": "true", | n | 111 | "publish_to_public": true, |
95 | "related_resource": [ | 112 | "related_resource": [ | ||
96 | "Harty, M.A., Forrestal, P.J., Watson, C.J., McGeough, K.L., | 113 | "Harty, M.A., Forrestal, P.J., Watson, C.J., McGeough, K.L., | ||
97 | Carolan, R., Elliot, C., Krol, D., Laughlin, R.J., Richards, K.G. & | 114 | Carolan, R., Elliot, C., Krol, D., Laughlin, R.J., Richards, K.G. & | ||
98 | Lanigan, G.J., 2016. Reducing nitrous oxide emissions by changing N | 115 | Lanigan, G.J., 2016. Reducing nitrous oxide emissions by changing N | ||
99 | fertiliser use from calcium ammonium nitrate (CAN) to urea based | 116 | fertiliser use from calcium ammonium nitrate (CAN) to urea based | ||
100 | formulations. Science of the Total Environment, 563\u2013564, | 117 | formulations. Science of the Total Environment, 563\u2013564, | ||
101 | pp.576\u2013586. https://doi.org/10.1016/j.scitotenv.2016.04.120", | 118 | pp.576\u2013586. https://doi.org/10.1016/j.scitotenv.2016.04.120", | ||
102 | "Rahman, N., Richards, K.G., Harty, M.A., Watson, C.J., Carolan, | 119 | "Rahman, N., Richards, K.G., Harty, M.A., Watson, C.J., Carolan, | ||
103 | R., Krol, D., Lanigan, G.J. & Forrestal, P.J., 2021. Differing effects | 120 | R., Krol, D., Lanigan, G.J. & Forrestal, P.J., 2021. Differing effects | ||
104 | of increasing calcium ammonium nitrate, urea and urea + NBPT | 121 | of increasing calcium ammonium nitrate, urea and urea + NBPT | ||
105 | fertiliser rates on nitrous oxide emission factors at six temperate | 122 | fertiliser rates on nitrous oxide emission factors at six temperate | ||
106 | grassland sites in Ireland. Agriculture, Ecosystems & Environment, | 123 | grassland sites in Ireland. Agriculture, Ecosystems & Environment, | ||
107 | 313, 107382. https://doi.org/10.1016/j.agee.2021.107382" | 124 | 313, 107382. https://doi.org/10.1016/j.agee.2021.107382" | ||
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